Low-temperature crystallization of phase-pure α-formamidinium lead iodide enabled by study in Science Advances

This was published on May 11, 2021

Perovskite solar cells (PSCs) are among the most promising and cheapest photovoltaic technologies now available, but widespread application has been hampered by issues linked to long-term stability and processability. In the paper A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3, recently published in Science Advances, researchers including Prof. Michele Parrinello, professor of computational Sciences at the Università della Svizzera italiana and ETHZ as well as Group Leader in NCCR MARVEL's Design & Discovery Project 1, and Paramvir Ahlawata PhD student in the EPFL Lab of Prof. Ursula Reothlisberger, address this problem with a combined experimental and simulation study that could improve the design of industrial-scale processing techniques for MAPbI3 and FAPbI3, two lead perovskites.

by Carey Sargent, NCCR MARVEL, EPFL

Though different fabrication approaches exist, two-step deposition is one of the main experimental techniques now used to make efficient, stable PSCs, especially on the industrial scale. The process involves first depositing lead iodide (PbI2) and then adding halide salts of monovalent cations such as methylammonium iodide (MAI) and formamidinium iodide (FAI) to convert it to perovskite.  

While this two-step deposition is better than other options, it is difficult to maintain reproducible high performance and long-term stability when scaling up, mostly because of a lack of control over the fabrication process. Gaining an understanding of the mechanism behind halide perovskite crystallization at the atomic level is therefore essential.  

In the paper A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3 the authors chose to study, to this end, the two-step fabrication of methylammonium lead iodide (MAPbI3) and formamidinium lead iodide (FAPbI3).

Figure 1. Phase transition via intermediate phases.

While the former is a well-studied system, the latter was chosen because of attractive features including a ∼1.45-eV bandgap, high-charge carrier mobility, and superior thermal stability that appear in its α-FAPbI3 polymorph. The problem with this perovskite however is that the α phase is metastable and the thermodynamic phase transition requires high temperatures of around 150 degrees Celsius. The combined experimental and theoretical study, published in the 23 April issue of Science Advances, uncovered the microscopic details of the crystallization process, leading the way to the discovery of a low-temperature pathway to the fabrication of the material.   

While previous experimental research on MAPbI3 revealed that the two-step process occurs via intercalation of the MA+ cations in PbI2 layers followed by a transformation to the perovskite structure via intermediate phases, the experiments couldn’t resolve the nature of these intermediate phases or clarify the underlying atomistic mechanism. Using a molecular dynamics (MD) investigation based on an enhanced sampling technique called metadynamics (WTMetaD), the team found that that transformation takes place through a sequence of intermediates. The theoretical results were in line with experiments, encouraging the researchers to investigate whether a similar process was also behind the transformation of α-FAPbI3. Starting from simulations, they discovered that a two-step process is indeed possible at lower temperatures in this material. A series of in situ x-ray and thin-film experiments then confirmed this result and enabled the low-temperature formation of phase-pure α -FAPbI3 thin films.  

References: 

P. Ahlawat, A. Hinderhofer, E. A. Alharbi, H. Lu,  A. Ummadisingu, H. Niu, M. Invernizzi, S. Mohammed Zakeeruddin, M. Ibrahim Dar, F. Schreiber, A. Hagfeldt, M. Grätzel, U. Rothlisberger, and M. Parrinello,  A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3 , Science Advances, 23, 7, 17 (2021) 


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